Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05551f Click here for additional data file.

Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds† †Electronic supplementary information (ESI) available. CCDC 1028432. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03128h Click here for additional data file. Click here for additional data file.

Enhancing the reactivity of nickel(ii) in hydrogen evolution reactions (HERs) by β-hydrogenation of porphyrinoid ligands† †Electronic supplementary information (ESI) available. CCDC 1528290, 1554494 and 1554445. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc02073b Click here for additional data file. Click here for additional data file.

Neutral iridium catalysts with chiral phosphine-carboxy ligands for asymmetric hydrogenation of unsaturated carboxylic acids† †Electronic supplementary information (ESI) available: For CIF data of (S)-2d, experimental procedures, and characterization data. CCDC 1498903. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03764j Click here for additional data file. Click here for additional data file.

Neutral Iridium Catalysts with Chiral Phosphine-Carboxy Ligands for Asymmetric Hydrogenation of Unsaturated Carboxylic Acids Shuang Yang, Wen Che, Hui-Ling Wu, Shou-Fei Zhu* and Qi-Lin Zhou* a State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, ...

Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts.

Ligand control of metal nanoparticles (MNPs) is rapidly gaining importance as ligands can stabilize the MNPs and regulate their catalytic properties. Herein we report the first example of Pt NPs ligated by imidazolium-amidinate ligands that bind strongly through the amidinate anion to the platinum surface atoms. The binding was established by 15N NMR spectroscopy, a precedent for nitrogen ligan...

Pd-catalyzed asymmetric hydrogenation of fluorinated aromatic pyrazol-5-ols via capture of active tautomers† †Electronic supplementary information (ESI) available. CCDC 1040656–1040658. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00835b Click here for additional data file. Click here for additional data file.